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首页 > 期刊论文 > 铝合金摩擦性能的研究论文

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Nicole20041414

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镁是最轻的结构金属。几种常用结构金属的密度(g·cm-3)(20o)如下: AL Mg Ti Fe Cu 可见镁的密度约分为Al,Ti,Fe,Cu的64%,39%,22%,19%。由于镁的密度小,它的合金也以质轻著称。一般镁合金的密度在·cm-3以下,镁,锂合金的密度低于镁 ·cm-3.某些超轻型镁.锂合金密度甚至低于1,比水还轻.镁得镁和金的低密度使其比性能提高.例如,20o时的弹性模量为45Gpa,比铝(70Gpa)和Ti(120Gpa)的低,但三者的比弹性模量相同(~26Gpa).镁和镁合金质量小的特点,使其在交通运输、航空工业和航天工业上具有巨大的应用前景.镁的熔点为 651℃,沸点为1107℃.镁的蒸气压很高,627℃时为℃时为,因此镁铍极易挥发.镁原子最外层的两个电子很易失去,是很活泼的金属.常温下镁能与F、CL、BR、I等元素作用生成相应化合物.加热时镁能与硫、氮作用生成MgS和Mg3N2。在空气中镁会慢慢氧化,失去银白光泽而变黑.若温度提高至400℃以上,镁的氧化速度增快,超过500℃以后氧化速度更快,会着火燃烧,此时会生成氧化镁和少量氮化镁.镁燃烧时会发出非常强烈的光亮.镁的这一特点,颇受人们的青睐.早期就被利用于摄影照明,给人们留下美好的形象和记忆.战争时期,被用来制造照明 弹,把战场和目标照明得如同白昼.又被用于制造燃烧 弹,点燃战区的物资装备,杀伤对方有生力量.人们还利用镁的这一特点,将镁粉、铝粉和其它原料制成烟花.每当节庆的夜晚,随着阵阵悦耳响声,人们可以看到”嫦娥奔月””天女散花”……各种形色的烟花在夜空飞舞,多彩多姿,给人们带来极大的欢乐.顺便提一下,镁的这种”牺牲自我””乐于助人”精神处处可见.例如它仗着活泼的电化学性质做了牺牲自我的阳极,保护着其它的金属和设备.它又作为原电池阳极,耗尽了自己,照亮了他人.由于化学活泼性高,金属镁是耐腐蚀性能最差的金属之一.在酸性、中性和弱碱性溶液中它都会受到腐蚀而变成Mg2+离子.各种类型大气均会对镁产生程度不同的腐蚀作用.在干燥的空气中,它的表面上形成一层暗淡的的疏松多孔氧化膜,在潮湿大气中,生成的产物组成大致为Mgco3·3H2O+Mgso4·7H2o+Mg(OH)2.大气湿度增加,工为地区和海洋环境的大气中所含的二氧化硫和氯化物等物质,能加重镁的腐蚀.镁中氯化物杂质及铁杂质也会加速镁的腐蚀.因此,工业生产的镁锭必须镀膜钝化,涂油及以蜡纸包覆. 镁是地壳中分布最广的元素之一,占地壳重量的,为第四个最丰富的金属元素(位于Al、Fe、Ca)之后.在自然界中镁只能以化合物的形态存在.在已知的1500多种矿物中,含镁矿物的有200多种,主要为碳酸盐、硅酸盐、硫酸盐、氧化物.海洋及盐湖中的镁比陆地上更多,是镁的主要来源.海水中含有10多种元素,镁的含量排第三,位居Na、K之后.海水中含镁每立方千米海水中有130万t镁,相当于世界镁年消耗量的4倍(见表)盐湖水的镁浓度比海水更高.以东以色列、约旦之间的”死海”(实为另一内陆湖),受到千万干旱气候的造化,湖水极浓,含镁竟高达4%.仅此一处的镁,就能满足全世界万年的需要. 纯镁不适合做结构材料.作为结构材料应用的镁主要是镁合金和铝-镁合金.全世界约有千种铝合金牌号,若按化学成份归类的话,约为300多种.这300多种铝合金几乎都含有镁,其中以镁作为主要添加剂的铝-镁合金(镁含量最高为)约为40种.全世界各国镁合金品牌共有200多种,这些品牌按化学成份可归为30多种.共中变形镁合金黄色10多种,铸造镁合金20多种,铸造镁合金主要有以下3个体系. 1) 镁-铝合金.这种合金自第一次世界大战被德国使用以来,成了最广泛使用的铸造镁合金的基础.大部份含有8%~9%的铝及少量的锌(使拉伸性能有某些提高)和锰(改善抗蚀性)2) 镁-铝-锌合金.镁-铝合金中加锌会产生一定的强化作用,其中高含锌量的合金具有很吸引人的压铸特性.如Mg-8AL-8ZN,具有足够大的流动性.,可用于压铸件,而且流动性和抗蚀性超过传统铝-锌合金.3) 含锆镁合金.锆能细化晶粒,改善镁合金的拉伸性能,提高镁合金蠕变能力,以满足航空和航天工业的需要.属于这一系列的合金有镁-锌-锆合金,镁-稀土-锌-锆合金,以及镁-钍系为基和镁-银系为基的含ZR合金.这种含稀土金属和或含钍的合金都可焊.钍也能改善铸造性能.银可以进一步提高拉伸性能.一些铸造镁合金的性能示于表.镁是立方晶格的金属,可以承受的形变量有限(特别是在低温下).其变形材料主要在300~500℃温度范围内通过挤压、;轧制和压力锻造进行生产.变形合金可以按照它们是否含锆而分成两类.按照变形产品种类可分为三类:1薄板和厚板轧制金.如AZ31(Mg-Al-Z系),ZM21(Mg-Zn-Mn系)和ZE10(Mg-Zn-RE系),这三种合金都可焊,后两种强度较低.LA141A(Mg-Li-Al)等也属这一类,前面已作详细介绍.属于这一类的还有含钍的HK31(Mg-Th-Zr系)以及随后研制的HM21(Mg-Th-Mn等),它们的高温强度更高.2挤压合金.这类合金含铝量大多在1%~8%之间.镁合金都具有密度小的特点,特别是某些镁-锂合金(见前),密度甚至低于1。美英俄等国正在研制含钇镁合金。一种合金,其密度小于·cm-3 ,抗拉强密度420Mpa, 屈服强度360Mpa,比现有任何一种变形镁合金的都高,同高强度铝合金强度相当。 镁铝合金又名铝镁合金,分子式:Mg4Al3分子量:颜色为灰褐色,比重约为,熔点463℃,燃烧时产生的温度达2000℃-3000℃。在烟花生产过程中起着非常重要的还原剂作用,也可作为白光剂和照明剂。镁铝合金是用镁锭和铝锭在保护气体中高温熔融而成。长期以来关于镁铝合金的结构有两种说法。一种说法是镁铝合金是简单物理混合;另一种说法是镁铝合金内部改变了晶体结构,不是简单的物理混合。镁锭和铝锭在高于1150K时,部分铝与空气中的氧气反应,生成a-Al2O3,氧化铝的此种晶体化学性质呈惰性,起着屏障、隔离作用。低于1150K时,生在B-Al2O3而这种晶体与酸反应,保护不了内部的镁铝合金。标准的镁铝合金中镁、铝的含量各约为50%。活性铝含量的多少对烟花的安全生产和产品的质量有很大的影响。但是现在生产镁铝合金的企业多为私营企业,近几年来铝锭比镁锭贵,受利益的驱动,大多未按国标生产。现在镁铝合金粉中铝的含量普遍低于50%,有的铝含量低到了40%。镁含量的增加使得镁铝合金的性质接近镁粉的性质,使得烟火 药的撞击感度、摩擦感度增加,烟火剂更加敏感,从而增加隐患。我们可能以用下面的化学机理来检验镁铝合金中铝的含量。1、盐酸与镁铝合金的反应Mg+2HCl=MgCl2+H2↑2Al+6HCl=2AlCl3+3H2↑2、混合溶液与氢氧化钠溶液反应(混合溶液中滴几滴石蕊或酚酞试剂作指示剂,以避免氢氧化钠过量)MgCl2+2NaOH=2NaCl+Mg(OH)2↓AlCl3+3NaOH=3NaCl+Al(OH)3↓3、过滤、烘干、称重,重量为G1克4、氢氧化铝与过量的氢氧化钠反应Al(OH)3+NaOH=NaAlO2+2H2O5、未反应的为氢氧化镁。过滤、烘干、称重,重量为G2克镁铝合金的中铝的含量 Al%=(G1-G2)/G×规定了镁铝合金中铝的含量的范围为47-53%,铝含量低于这个范围镁铝合金容易引起质量事故和安全事故,应慎用。镁锭在镁铝合金中的应用:镁铝合金由镁锭和铝锭在保护气体中高温熔融而成,其组成有:简单的物理混合与已改变晶体结构的物理混合两种说法。

132 评论

abc123459876

This experimental study content is melts the aging treatment of metal to 2014 aluminum alloy organizational structure, mechanics performance and the friction performance influence. To used the different melting aging treatment of metal craft the aluminum alloy test specimen and the primitive test specimen has carried on a series of experiments, first carried on the impact, the pulling test to the primitive test specimen, determined the primitive test specimen mechanics performance: Tensile strength σb, yield strength σ, elongation ratio delta and impact tenacity ak; Next to passes through the different melting aging treatment of metal craft test specimen and the primitive test specimen carries on the attrition performance experiment and the Brinell hardness survey, from this analyzes the comparison melting aging treatment of metal to 2014 aluminum alloy sample mechanics performance and the friction performance the test specimen microstructure change under the metallography microscope, the contrast, the observation, the analysis research draws the conclusion. The experimental study indicated that,May know after the analysis, after 2014 aluminum alloy melting aging treatment of metal, the existence quite complex, the main alloy is: W (Cu4Mg5Si4Al), theta (CuAl2), Mg2Si, CuMgAl2, inclusion (FeMnSi)Al6 and 500 ℃ meltings, 165 ℃ aging treatments of metal, 2014 aluminum alloy alloy distribute are tiny, are even, when wears, the polishing scratches are shallowest, the wearing capacity is smallest, the resistance to wear is best, degree of hardness is highest. The overall mentions, after the process melting aging treatment of metal 2014 aluminum alloy separation are more second, causes its resistance to wear and the skin hardness along with the melting temperature, the alloying element proliferation dissolves fully, makes the substrate metal the dislocated density to increase, the crystal lattice has the distortion, simultaneously the alloying element also can change the solid solution elasticity coefficient, the diffusion coefficient, the cohesive force and the atomic arrangement flaw, causes the dislocated line to change curved, the dislocation resistance of motion increases, causes the material aluminum alloys belong to the precipitation to strengthen the alloy, mainly depends on in the melting, the effectiveness process separates out the precipitation from the oversaturation solid solution to along with the melting temperature increment, after effectiveness separates out increases also even, after the alloy intensity elevates first drops, appears the peak value.

284 评论

pisces850318

题目翻译如下Time of experiment impacts of the effectiveness for a given period of time treatment studying content is solid dissolve over 2014 aluminium alloy frameworks of organization , Mechanics functions and friction functions.第一段翻译如下The sell the handicraft aluminium alloy sample at reduced prices and primitive sample of effectiveness for a given period of time has carried out the experiment a train of on to adopt a block of wood and strengthening to dissolve, function carrying out Mechanics pounding , coming ascertain the tensile test, the primitive sample on primitive sample first: Tensile strength sigmab, knuckles under intensity , elongation rate dleta and pounds tenacity ak; Secondly, the sell the handicraft sample at reduced prices and primitive sample of effectiveness for a given period of time carries out the measurement wearing the function experiment and Brinell hardness away on to dissolving course not strengthening together , comes to analyse comparison from this solid dissolve effectiveness for a given period of time handles the effect to 2014 aluminium alloy sample Mechanics functions and friction functions. The metallographic observing a sample organizes change , contrast , observe under metallographic microscope, analyse the come to reach a conclusion studying.第二段翻译如下Experiment go into is indicated: Analysis but knowledges , 2014 aluminium alloys strengthens a course dissolving effectiveness for a given period of time handles the queen , existence compares complicated, the main alloy is each other: W looks at and appraises (Cu4Mg5Si4Al) , the theta looks at and appraises (CuAl2) , Mg2Si , CuMgAl2 , mixed sundries (FeMnSi) Al6 and Mg3SiAl2. 500 ~C strengthens classics dissolving , 165 ~C effectiveness for a given period of time handles the queen, polishing scratch is the most shallow , the amounts wearing away are minimal , abrasion resistance is best , the hardness is maximal when each other, 2014 aluminium alloys scatter trivial , homogeneous , wear away.第三段翻译如下Population is strengthened as a matter of fact , through dissolving that effectiveness for a given period of time handles 2014 aluminium alloy of the queen separates more second phases out , uses whose abrasion resistance and surface hardness rise. With solid dissolve temperature rise, the resolving the alloying element is diffused is more sufficient , the place wrong density making base experience and observe metal increases by , distortion happened in the crystal lattice, the alloying element is able to change the solid solution coefficient of elasticity at the same time , that the modulus , cohesive force and atom diffusing arrange a defect, makes the place wrong be changed into turn gleam , the material increasing , arousing place wrong motion resistance intensifies. 2014 aluminium alloys belong to precipitayion strengthen the type alloy , dissolving depending on strengthening mainly , come to intensify each other in effectiveness for a given period of time process from separating precipitayion out in oversaturation solid solution. Another is strengthened subsequently dissolving the temperature rises , the effectiveness for a given period of time queen is separated out each other increase by and homogeneous , peak value comes down , appears after the alloy intensity rises first.文章有些长、、望认真看完、、标准人工翻译、、希望可以帮助你、、

276 评论

Lena睡美梦

This experimental study content is melts the aging treatment of metal to 2014 aluminum alloy organizational structure, mechanics performance and the friction performance used the different melting aging treatment of metal craft the aluminum alloy test specimen and the primitive test specimen has carried on a series of experiments, first carried on the impact, the pulling test to the primitive test specimen, determined the primitive test specimen mechanics performance: Tensile strength σb, yield strength σ, elongation ratio delta and impact tenacity ak; Next to passes through the different melting aging treatment of metal craft test specimen and the primitive test specimen carries on the attrition performance experiment and the Brinell hardness survey, from this analyzes the comparison melting aging treatment of metal to 2014 aluminum alloy sample mechanics performance and the friction performance the test specimen microstructure change under the metallography microscope, the contrast, the observation, the analysis research draws the experimental study indicated that,May know after the analysis, after 2014 aluminum alloy melting aging treatment of metal, the existence quite complex, the main alloy is: W (Cu4Mg5Si4Al), theta (CuAl2), Mg2Si, CuMgAl2, inclusion (FeMnSi)Al6 and Mg3SiAl2.经500 ℃固溶、165 ℃时效处理后,2014 铝合金合金相分布细小、均匀,磨损时,磨痕最浅,磨损量最小,耐磨性最好,硬度最高。The overall mentions, after the process melting aging treatment of metal 2014 aluminum alloy separation are more second, causes its resistance to wear and the skin hardness enhancement.随固溶温度提高,合金元素扩散溶解更充分,使基体金属的位错密度增加,晶格发生畸变,同时合金元素还会改变固溶体弹性系数,扩散系数、内聚力和原子排列缺陷,使位错线变弯,位错运动阻力增加,引起材料强化。2014 铝合金属于沉淀强化型合金,主要靠固溶、时效过程中从过饱和固溶体中析出沉淀相来强化。另外随着固溶温度升高,时效后析出相增多且均匀,合金强度先升高后下降,出现峰值。

302 评论

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